Fabrication of large-area ordered Au nano-ring arrays for the electrochemical removal and sensing of rhodamine 6G molecules

To understand the formation process of ordered Au nano-ring arrays (NRA), a series of factors—including etchant gas and flow rate, chamber pressure and RF power—were systematically studied and a set of optimum parameters were deduced to fabricate this interesting structure. With plenty of active sit...

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Bibliographic Details
Main Author: Cao, Xun
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2024
Subjects:
Online Access:https://hdl.handle.net/10356/174001
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Institution: Nanyang Technological University
Language: English
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Summary:To understand the formation process of ordered Au nano-ring arrays (NRA), a series of factors—including etchant gas and flow rate, chamber pressure and RF power—were systematically studied and a set of optimum parameters were deduced to fabricate this interesting structure. With plenty of active sites previously reported, a new role of ordered Au NRA is unlocked in this work. The ordered Au NRA could perform the electrochemical removal of rhodamine 6G (R-6G) at a high concentration in seawater within 12 min and complete discoloration within 9 min, which demonstrates ~7 times efficiency improvement from previous studies. The nanostructured surface also makes the ordered Au NRA a good substrate material in R-6G sensing using surface-enhanced Raman spectroscopy, which performs with better accuracy than the ultraviolet–visible light technique.