Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions

Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reac...

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Main Authors: Kong, Xin Ying, Li, Chenfei, Choo, Shao Rong, Lyu, Maoping, Soo, Han Sen
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2024
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Online Access:https://hdl.handle.net/10356/174761
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1747612024-04-12T15:32:15Z Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions Kong, Xin Ying Li, Chenfei Choo, Shao Rong Lyu, Maoping Soo, Han Sen School of Chemistry, Chemical Engineering and Biotechnology Engineering Energy Environmental sciences Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reactions, followed by a continuous, segmented flow system for gram-scale upcycling into value-added platform chemicals. This protocol, employing tandem carbon-hydrogen bond oxidation/carbon-carbon bond cleavage reactions, can be useful for photocatalytically transforming plastics at ambient conditions. For complete details on the use and execution of this protocol, please refer to Li et al. (2023). Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University National Research Foundation (NRF) Published version H.S.S. acknowledges that this project was supported by A*STAR under the AME IRG grant A2083c0050. H.S.S. thanks ExxonMobil for supporting this project through the Singapore Energy Center grant EM11161.TO24. H.S.S. also thanks the support from the Ministry of Education (Singapore) Academic Research Fund Tier 1 Grant RG 09/22 and the Nanyang Technological University (NTU) 5th Accelerating Creativity and Excellence Grant. H.S.S. acknowledges that this project was partly supported by the National Research Foundation (NRF) Singapore under the grant NRFCRP27-2021-0001. 2024-04-09T05:24:26Z 2024-04-09T05:24:26Z 2024 Journal Article Kong, X. Y., Li, C., Choo, S. R., Lyu, M. & Soo, H. S. (2024). Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions. STAR Protocols, 5(1), 102918-. https://dx.doi.org/10.1016/j.xpro.2024.102918 2666-1667 https://hdl.handle.net/10356/174761 10.1016/j.xpro.2024.102918 38412103 2-s2.0-85187954271 1 5 102918 en A2083c0050 EM11161.TO24 RG 09/22 NRF-CRP27-2021-0001 STAR protocols © 2024 The Author(s). This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering
Energy
Environmental sciences
spellingShingle Engineering
Energy
Environmental sciences
Kong, Xin Ying
Li, Chenfei
Choo, Shao Rong
Lyu, Maoping
Soo, Han Sen
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
description Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reactions, followed by a continuous, segmented flow system for gram-scale upcycling into value-added platform chemicals. This protocol, employing tandem carbon-hydrogen bond oxidation/carbon-carbon bond cleavage reactions, can be useful for photocatalytically transforming plastics at ambient conditions. For complete details on the use and execution of this protocol, please refer to Li et al. (2023).
author2 School of Chemistry, Chemical Engineering and Biotechnology
author_facet School of Chemistry, Chemical Engineering and Biotechnology
Kong, Xin Ying
Li, Chenfei
Choo, Shao Rong
Lyu, Maoping
Soo, Han Sen
format Article
author Kong, Xin Ying
Li, Chenfei
Choo, Shao Rong
Lyu, Maoping
Soo, Han Sen
author_sort Kong, Xin Ying
title Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
title_short Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
title_full Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
title_fullStr Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
title_full_unstemmed Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
title_sort protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
publishDate 2024
url https://hdl.handle.net/10356/174761
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