Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions
Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reac...
Saved in:
Main Authors: | , , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2024
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/174761 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
id |
sg-ntu-dr.10356-174761 |
---|---|
record_format |
dspace |
spelling |
sg-ntu-dr.10356-1747612024-04-12T15:32:15Z Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions Kong, Xin Ying Li, Chenfei Choo, Shao Rong Lyu, Maoping Soo, Han Sen School of Chemistry, Chemical Engineering and Biotechnology Engineering Energy Environmental sciences Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reactions, followed by a continuous, segmented flow system for gram-scale upcycling into value-added platform chemicals. This protocol, employing tandem carbon-hydrogen bond oxidation/carbon-carbon bond cleavage reactions, can be useful for photocatalytically transforming plastics at ambient conditions. For complete details on the use and execution of this protocol, please refer to Li et al. (2023). Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University National Research Foundation (NRF) Published version H.S.S. acknowledges that this project was supported by A*STAR under the AME IRG grant A2083c0050. H.S.S. thanks ExxonMobil for supporting this project through the Singapore Energy Center grant EM11161.TO24. H.S.S. also thanks the support from the Ministry of Education (Singapore) Academic Research Fund Tier 1 Grant RG 09/22 and the Nanyang Technological University (NTU) 5th Accelerating Creativity and Excellence Grant. H.S.S. acknowledges that this project was partly supported by the National Research Foundation (NRF) Singapore under the grant NRFCRP27-2021-0001. 2024-04-09T05:24:26Z 2024-04-09T05:24:26Z 2024 Journal Article Kong, X. Y., Li, C., Choo, S. R., Lyu, M. & Soo, H. S. (2024). Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions. STAR Protocols, 5(1), 102918-. https://dx.doi.org/10.1016/j.xpro.2024.102918 2666-1667 https://hdl.handle.net/10356/174761 10.1016/j.xpro.2024.102918 38412103 2-s2.0-85187954271 1 5 102918 en A2083c0050 EM11161.TO24 RG 09/22 NRF-CRP27-2021-0001 STAR protocols © 2024 The Author(s). This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). application/pdf |
institution |
Nanyang Technological University |
building |
NTU Library |
continent |
Asia |
country |
Singapore Singapore |
content_provider |
NTU Library |
collection |
DR-NTU |
language |
English |
topic |
Engineering Energy Environmental sciences |
spellingShingle |
Engineering Energy Environmental sciences Kong, Xin Ying Li, Chenfei Choo, Shao Rong Lyu, Maoping Soo, Han Sen Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
description |
Upcycling plastics presents an opportunity not only to reduce plastic waste, but also to provide an alternative carbon source to fossil fuels. Herein, we present a protocol to upcycle plastics with resin codes 2-7 using a commercially available base-metal photocatalyst. We first conducted batch reactions, followed by a continuous, segmented flow system for gram-scale upcycling into value-added platform chemicals. This protocol, employing tandem carbon-hydrogen bond oxidation/carbon-carbon bond cleavage reactions, can be useful for photocatalytically transforming plastics at ambient conditions. For complete details on the use and execution of this protocol, please refer to Li et al. (2023). |
author2 |
School of Chemistry, Chemical Engineering and Biotechnology |
author_facet |
School of Chemistry, Chemical Engineering and Biotechnology Kong, Xin Ying Li, Chenfei Choo, Shao Rong Lyu, Maoping Soo, Han Sen |
format |
Article |
author |
Kong, Xin Ying Li, Chenfei Choo, Shao Rong Lyu, Maoping Soo, Han Sen |
author_sort |
Kong, Xin Ying |
title |
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
title_short |
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
title_full |
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
title_fullStr |
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
title_full_unstemmed |
Protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
title_sort |
protocol for photocatalytic upcycling of non-biodegradable plastics into platform chemicals at ambient conditions |
publishDate |
2024 |
url |
https://hdl.handle.net/10356/174761 |
_version_ |
1806059856816242688 |