A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing
Strengthening materials via conventional "top-down" processes generally involves restricting dislocation movement by precipitation or grain refinement, which invariably restricts the movement of dislocations away from, or towards, a crack tip, thereby severely compromising their fracture r...
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sg-ntu-dr.10356-1749122024-04-20T16:49:35Z A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing Kumar, Punit Huang, Sheng Cook, David H. Chen, Kai Ramamurty, Upadrasta Tan, Xipeng Ritchie, Robert O. School of Mechanical and Aerospace Engineering Institute of Materials Research and Engineering, A*STAR Engineering Crystal structure Fracture resistance Strengthening materials via conventional "top-down" processes generally involves restricting dislocation movement by precipitation or grain refinement, which invariably restricts the movement of dislocations away from, or towards, a crack tip, thereby severely compromising their fracture resistance. In the present study, a high-entropy alloy Al0.5CrCoFeNi is produced by the laser powder-bed fusion process, a "bottom-up" additive manufacturing process similar to how nature builds structures, with the microstructure resembling a nano-bridged honeycomb structure consisting of a face-centered cubic (fcc) matrix and an interwoven hexagonal net of an ordered body-centered cubic B2 phase. While the B2 phase, combined with high-dislocation density and solid-solution strengthening, provides strength to the material, the nano-bridges of dislocations connecting the fcc cells, i.e., the channels between the B2 phase on the cell boundaries, provide highways for dislocation movement away from the crack tip. Consequently, the nature-inspired microstructure imparts the material with an excellent combination of strength and toughness. Agency for Science, Technology and Research (A*STAR) Published version This work was primarily supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division under contract no. DE-AC02-05-CH11231 to the Damage-Tolerance in Structural Materials Program (KC13) at the Lawrence Berkeley National Laboratory (LBNL). S.H. and U.R. acknowledge the support of the Structural Metal Alloys Program (Grant reference no. A18B1b0061) of the Agency for Science, Technology and Research of Singapore. D.H.C. acknowledges support of an NSF Graduate Fellowship from the National Science Foundation under Grant No. DGE 2146752. X.T. acknowledges the support of NUS Start-up Fund (22-5928-A0001) and Singapore Ministry of Education Academic Research Fund Tier 1 grant (22-4902- A0001). 2024-04-16T02:26:46Z 2024-04-16T02:26:46Z 2024 Journal Article Kumar, P., Huang, S., Cook, D. H., Chen, K., Ramamurty, U., Tan, X. & Ritchie, R. O. (2024). A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing. Nature Communications, 15(1), 841-. https://dx.doi.org/10.1038/s41467-024-45178-2 2041-1723 https://hdl.handle.net/10356/174912 10.1038/s41467-024-45178-2 38286856 2-s2.0-85183661147 1 15 841 en A18B1b0061 Nature Communications This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply 2024. Open Access. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/ licenses/by/4.0/. application/pdf |
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Engineering Crystal structure Fracture resistance Kumar, Punit Huang, Sheng Cook, David H. Chen, Kai Ramamurty, Upadrasta Tan, Xipeng Ritchie, Robert O. A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
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Strengthening materials via conventional "top-down" processes generally involves restricting dislocation movement by precipitation or grain refinement, which invariably restricts the movement of dislocations away from, or towards, a crack tip, thereby severely compromising their fracture resistance. In the present study, a high-entropy alloy Al0.5CrCoFeNi is produced by the laser powder-bed fusion process, a "bottom-up" additive manufacturing process similar to how nature builds structures, with the microstructure resembling a nano-bridged honeycomb structure consisting of a face-centered cubic (fcc) matrix and an interwoven hexagonal net of an ordered body-centered cubic B2 phase. While the B2 phase, combined with high-dislocation density and solid-solution strengthening, provides strength to the material, the nano-bridges of dislocations connecting the fcc cells, i.e., the channels between the B2 phase on the cell boundaries, provide highways for dislocation movement away from the crack tip. Consequently, the nature-inspired microstructure imparts the material with an excellent combination of strength and toughness. |
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School of Mechanical and Aerospace Engineering |
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School of Mechanical and Aerospace Engineering Kumar, Punit Huang, Sheng Cook, David H. Chen, Kai Ramamurty, Upadrasta Tan, Xipeng Ritchie, Robert O. |
format |
Article |
author |
Kumar, Punit Huang, Sheng Cook, David H. Chen, Kai Ramamurty, Upadrasta Tan, Xipeng Ritchie, Robert O. |
author_sort |
Kumar, Punit |
title |
A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
title_short |
A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
title_full |
A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
title_fullStr |
A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
title_full_unstemmed |
A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing |
title_sort |
strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3d-printing |
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2024 |
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https://hdl.handle.net/10356/174912 |
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1800916178811486208 |