Synthesis of ligands for 2D organometallic networks

The focus of this project is the synthesis and characterization of an symmetric imine containing ligand for a 2D organometallic network with transition metals, which can be used as a catalyst. Over the course of this project, methodologies like condensation reaction and nucleophilic aromatic substit...

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書目詳細資料
主要作者: Liew, Mabelyn Zi Xuan
其他作者: Andrew Clive Grimsdale
格式: Final Year Project
語言:English
出版: Nanyang Technological University 2024
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在線閱讀:https://hdl.handle.net/10356/176147
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機構: Nanyang Technological University
語言: English
實物特徵
總結:The focus of this project is the synthesis and characterization of an symmetric imine containing ligand for a 2D organometallic network with transition metals, which can be used as a catalyst. Over the course of this project, methodologies like condensation reaction and nucleophilic aromatic substitution were used to achieve the synthesis of ligands that will be used in the formation of said network. This report outlines attempts made to synthesise 2,3,8,9,14,15-hexabromo-5,6,11,12,17, 18-hexaazatrinaphthylene (ML1) and 2,3,8,9,14,15-hexakisthiobenzyl-5,6,11,12,17,18-hexaazatrinaphthylene (ML2). Recommendations at the end of this report include the bubbling the reagents for a longer period for ML1 and the use of a more reactive Chlorine (Cl) compound instead of Bromide (Br) to achieve the synthesis of ML2.