Synthesis of ligands for 2D organometallic networks

The focus of this project is the synthesis and characterization of an symmetric imine containing ligand for a 2D organometallic network with transition metals, which can be used as a catalyst. Over the course of this project, methodologies like condensation reaction and nucleophilic aromatic substit...

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Main Author: Liew, Mabelyn Zi Xuan
Other Authors: Andrew Clive Grimsdale
Format: Final Year Project
Language:English
Published: Nanyang Technological University 2024
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Online Access:https://hdl.handle.net/10356/176147
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1761472024-05-18T16:46:41Z Synthesis of ligands for 2D organometallic networks Liew, Mabelyn Zi Xuan Andrew Clive Grimsdale School of Materials Science and Engineering ACGrimsdale@ntu.edu.sg Engineering The focus of this project is the synthesis and characterization of an symmetric imine containing ligand for a 2D organometallic network with transition metals, which can be used as a catalyst. Over the course of this project, methodologies like condensation reaction and nucleophilic aromatic substitution were used to achieve the synthesis of ligands that will be used in the formation of said network. This report outlines attempts made to synthesise 2,3,8,9,14,15-hexabromo-5,6,11,12,17, 18-hexaazatrinaphthylene (ML1) and 2,3,8,9,14,15-hexakisthiobenzyl-5,6,11,12,17,18-hexaazatrinaphthylene (ML2). Recommendations at the end of this report include the bubbling the reagents for a longer period for ML1 and the use of a more reactive Chlorine (Cl) compound instead of Bromide (Br) to achieve the synthesis of ML2. Bachelor's degree 2024-05-14T05:08:01Z 2024-05-14T05:08:01Z 2024 Final Year Project (FYP) Liew, M. Z. X. (2024). Synthesis of ligands for 2D organometallic networks. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/176147 https://hdl.handle.net/10356/176147 en application/pdf Nanyang Technological University
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering
spellingShingle Engineering
Liew, Mabelyn Zi Xuan
Synthesis of ligands for 2D organometallic networks
description The focus of this project is the synthesis and characterization of an symmetric imine containing ligand for a 2D organometallic network with transition metals, which can be used as a catalyst. Over the course of this project, methodologies like condensation reaction and nucleophilic aromatic substitution were used to achieve the synthesis of ligands that will be used in the formation of said network. This report outlines attempts made to synthesise 2,3,8,9,14,15-hexabromo-5,6,11,12,17, 18-hexaazatrinaphthylene (ML1) and 2,3,8,9,14,15-hexakisthiobenzyl-5,6,11,12,17,18-hexaazatrinaphthylene (ML2). Recommendations at the end of this report include the bubbling the reagents for a longer period for ML1 and the use of a more reactive Chlorine (Cl) compound instead of Bromide (Br) to achieve the synthesis of ML2.
author2 Andrew Clive Grimsdale
author_facet Andrew Clive Grimsdale
Liew, Mabelyn Zi Xuan
format Final Year Project
author Liew, Mabelyn Zi Xuan
author_sort Liew, Mabelyn Zi Xuan
title Synthesis of ligands for 2D organometallic networks
title_short Synthesis of ligands for 2D organometallic networks
title_full Synthesis of ligands for 2D organometallic networks
title_fullStr Synthesis of ligands for 2D organometallic networks
title_full_unstemmed Synthesis of ligands for 2D organometallic networks
title_sort synthesis of ligands for 2d organometallic networks
publisher Nanyang Technological University
publishDate 2024
url https://hdl.handle.net/10356/176147
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