Toolsets for assessing ionic migration in halide perovskites
Halide perovskites, known for their tunable and exceptional optoelectronic properties, have been extensively explored for photovoltaics, light-emitting diodes, photodetectors, and memristors. With solar cell efficiencies closing on theoretical limits, stabilization of perovskite devices—especially v...
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sg-ntu-dr.10356-1784962024-06-25T15:37:37Z Toolsets for assessing ionic migration in halide perovskites Yantara, Natalia Mathews, Nripan School of Materials Science and Engineering Energy Research Institute @ NTU (ERI@N) Engineering Ionic migration Perovskite devices Photovoltaic Optoelectronic Halide perovskites, known for their tunable and exceptional optoelectronic properties, have been extensively explored for photovoltaics, light-emitting diodes, photodetectors, and memristors. With solar cell efficiencies closing on theoretical limits, stabilization of perovskite devices—especially via control of the ionic activity within the device—is a research gap that needs to be addressed before its commercialization. Solar cell stability is directly linked to ionic defects, and their effective passivation is essential for curbing ionic migration and associated deleterious effects. However, techniques to quantify and directly observe ionic migration are limited by the soft ionic lattice nature of the perovskite as well as its mixed ionic-electronic conductivity. This review examines both theoretical and experimental approaches to understand intrinsic and extrinsic ionic motion in halide perovskites at the material and device level. In addition to elemental and molecular analysis techniques that directly identify the ion in motion, spectroscopy techniques that measure properties associated with local stoichiometry changes have also been deployed. Measurement artifacts, strategies to mitigate their occurrence, as well as ways to differentiate electronic and ionic components related to specific techniques, are evaluated. Strict environmental control during measurement is highlighted due to perovskite’s sensitivity to external factors such as humidity, light, electric field, and heat. National Research Foundation (NRF) Submitted/Accepted version This research was supported by the National Research Foundation (NRF), Singapore, under its Competitive Research Program (CRP) (NRF-CRP25-2020-0002). 2024-06-24T08:20:44Z 2024-06-24T08:20:44Z 2024 Journal Article Yantara, N. & Mathews, N. (2024). Toolsets for assessing ionic migration in halide perovskites. Joule, 8(5), 1239-1273. https://dx.doi.org/10.1016/j.joule.2024.02.022 2542-4351 https://hdl.handle.net/10356/178496 10.1016/j.joule.2024.02.022 5 8 1239 1273 en NRF-CRP25-2020-0002 Joule © 2024 Elsevier Inc. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1016/j.joule.2024.02.022. application/pdf |
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Engineering Ionic migration Perovskite devices Photovoltaic Optoelectronic Yantara, Natalia Mathews, Nripan Toolsets for assessing ionic migration in halide perovskites |
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Halide perovskites, known for their tunable and exceptional optoelectronic properties, have been extensively explored for photovoltaics, light-emitting diodes, photodetectors, and memristors. With solar cell efficiencies closing on theoretical limits, stabilization of perovskite devices—especially via control of the ionic activity within the device—is a research gap that needs to be addressed before its commercialization. Solar cell stability is directly linked to ionic defects, and their effective passivation is essential for curbing ionic migration and associated deleterious effects. However, techniques to quantify and directly observe ionic migration are limited by the soft ionic lattice nature of the perovskite as well as its mixed ionic-electronic conductivity. This review examines both theoretical and experimental approaches to understand intrinsic and extrinsic ionic motion in halide perovskites at the material and device level. In addition to elemental and molecular analysis techniques that directly identify the ion in motion, spectroscopy techniques that measure properties associated with local stoichiometry changes have also been deployed. Measurement artifacts, strategies to mitigate their occurrence, as well as ways to differentiate electronic and ionic components related to specific techniques, are evaluated. Strict environmental control during measurement is highlighted due to perovskite’s sensitivity to external factors such as humidity, light, electric field, and heat. |
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School of Materials Science and Engineering |
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School of Materials Science and Engineering Yantara, Natalia Mathews, Nripan |
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Yantara, Natalia Mathews, Nripan |
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Yantara, Natalia |
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Toolsets for assessing ionic migration in halide perovskites |
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Toolsets for assessing ionic migration in halide perovskites |
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Toolsets for assessing ionic migration in halide perovskites |
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Toolsets for assessing ionic migration in halide perovskites |
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Toolsets for assessing ionic migration in halide perovskites |
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toolsets for assessing ionic migration in halide perovskites |
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2024 |
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https://hdl.handle.net/10356/178496 |
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