Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers

Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidiz...

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Main Authors: Hernando, Habib, Marpongahtun, Julianti, Elisa, Nuryawan, Arif, Amaturrahim, Suci Aisyah, Piliang, Averroes Fazlur Rahman, Yanhar, Muhammad Rafiq, Goei, Ronn, Soykeabkaew, Nattakan, Saputra, A. Muhammad Afdhal, Gea, Saharman
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2024
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Online Access:https://hdl.handle.net/10356/181338
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1813382024-11-29T15:47:14Z Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers Hernando, Habib Marpongahtun Julianti, Elisa Nuryawan, Arif Amaturrahim, Suci Aisyah Piliang, Averroes Fazlur Rahman Yanhar, Muhammad Rafiq Goei, Ronn Soykeabkaew, Nattakan Saputra, A. Muhammad Afdhal Gea, Saharman School of Materials Science and Engineering Engineering Bioplastic Crosslinking Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidized palm oil (CEPO). The bioplastics were formed using the solution casting method and analyzed for morphology, functional groups, diffraction peaks, thermal and mechanical properties, degradation time, and compostability. The optimal conditions were achieved with 30 % glycerol (Sample ST-CEPO-GLY30). The addition of glycerol enhances the thermal and mechanical properties, improves the biodegradability, and compostability of the bioplastics. Published version The authors would like to thank the rector of Universitas Sumatera Utara as its grants via TALENTA scheme program with given contract No. 1/UN5.2.3.1/PPM/KP-TALENTA/R/2023. Saharman Gea reports financial support was provided by Universitas Sumatera Utara. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. 2024-11-26T01:27:50Z 2024-11-26T01:27:50Z 2024 Journal Article Hernando, H., Marpongahtun, Julianti, E., Nuryawan, A., Amaturrahim, S. A., Piliang, A. F. R., Yanhar, M. R., Goei, R., Soykeabkaew, N., Saputra, A. M. A. & Gea, S. (2024). Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers. Case Studies in Chemical and Environmental Engineering, 10, 100839-. https://dx.doi.org/10.1016/j.cscee.2024.100839 2666-0164 https://hdl.handle.net/10356/181338 10.1016/j.cscee.2024.100839 2-s2.0-85198185913 10 100839 en Case Studies in Chemical and Environmental Engineering © 2024 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/). application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering
Bioplastic
Crosslinking
spellingShingle Engineering
Bioplastic
Crosslinking
Hernando, Habib
Marpongahtun
Julianti, Elisa
Nuryawan, Arif
Amaturrahim, Suci Aisyah
Piliang, Averroes Fazlur Rahman
Yanhar, Muhammad Rafiq
Goei, Ronn
Soykeabkaew, Nattakan
Saputra, A. Muhammad Afdhal
Gea, Saharman
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
description Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidized palm oil (CEPO). The bioplastics were formed using the solution casting method and analyzed for morphology, functional groups, diffraction peaks, thermal and mechanical properties, degradation time, and compostability. The optimal conditions were achieved with 30 % glycerol (Sample ST-CEPO-GLY30). The addition of glycerol enhances the thermal and mechanical properties, improves the biodegradability, and compostability of the bioplastics.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Hernando, Habib
Marpongahtun
Julianti, Elisa
Nuryawan, Arif
Amaturrahim, Suci Aisyah
Piliang, Averroes Fazlur Rahman
Yanhar, Muhammad Rafiq
Goei, Ronn
Soykeabkaew, Nattakan
Saputra, A. Muhammad Afdhal
Gea, Saharman
format Article
author Hernando, Habib
Marpongahtun
Julianti, Elisa
Nuryawan, Arif
Amaturrahim, Suci Aisyah
Piliang, Averroes Fazlur Rahman
Yanhar, Muhammad Rafiq
Goei, Ronn
Soykeabkaew, Nattakan
Saputra, A. Muhammad Afdhal
Gea, Saharman
author_sort Hernando, Habib
title Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
title_short Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
title_full Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
title_fullStr Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
title_full_unstemmed Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
title_sort impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
publishDate 2024
url https://hdl.handle.net/10356/181338
_version_ 1819112998638190592