Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers
Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidiz...
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sg-ntu-dr.10356-1813382024-11-26T01:27:50Z Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers Hernando, Habib Marpongahtun Julianti, Elisa Nuryawan, Arif Amaturrahim, Suci Aisyah Piliang, Averroes Fazlur Rahman Yanhar, Muhammad Rafiq Goei, Ronn Soykeabkaew, Nattakan Saputra, A. Muhammad Afdhal Gea, Saharman School of Materials Science and Engineering Engineering Bioplastic Crosslinking Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidized palm oil (CEPO). The bioplastics were formed using the solution casting method and analyzed for morphology, functional groups, diffraction peaks, thermal and mechanical properties, degradation time, and compostability. The optimal conditions were achieved with 30 % glycerol (Sample ST-CEPO-GLY30). The addition of glycerol enhances the thermal and mechanical properties, improves the biodegradability, and compostability of the bioplastics. Published version The authors would like to thank the rector of Universitas Sumatera Utara as its grants via TALENTA scheme program with given contract No. 1/UN5.2.3.1/PPM/KP-TALENTA/R/2023. Saharman Gea reports financial support was provided by Universitas Sumatera Utara. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. 2024-11-26T01:27:50Z 2024-11-26T01:27:50Z 2024 Journal Article Hernando, H., Marpongahtun, Julianti, E., Nuryawan, A., Amaturrahim, S. A., Piliang, A. F. R., Yanhar, M. R., Goei, R., Soykeabkaew, N., Saputra, A. M. A. & Gea, S. (2024). Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers. Case Studies in Chemical and Environmental Engineering, 10, 100839-. https://dx.doi.org/10.1016/j.cscee.2024.100839 2666-0164 https://hdl.handle.net/10356/181338 10.1016/j.cscee.2024.100839 2-s2.0-85198185913 10 100839 en Case Studies in Chemical and Environmental Engineering © 2024 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/). application/pdf |
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Engineering Bioplastic Crosslinking Hernando, Habib Marpongahtun Julianti, Elisa Nuryawan, Arif Amaturrahim, Suci Aisyah Piliang, Averroes Fazlur Rahman Yanhar, Muhammad Rafiq Goei, Ronn Soykeabkaew, Nattakan Saputra, A. Muhammad Afdhal Gea, Saharman Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
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Biodegradable bioplastics provide a promising solution to mitigate environmental harm from petroleum-based plastics. This study focuses on optimizing bioplastic films made from oil palm trunk starch (OPTS), using glycerol (10, 20, and 30 % v/w) as a plasticizer and modified with citric-acid epoxidized palm oil (CEPO). The bioplastics were formed using the solution casting method and analyzed for morphology, functional groups, diffraction peaks, thermal and mechanical properties, degradation time, and compostability. The optimal conditions were achieved with 30 % glycerol (Sample ST-CEPO-GLY30). The addition of glycerol enhances the thermal and mechanical properties, improves the biodegradability, and compostability of the bioplastics. |
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School of Materials Science and Engineering |
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School of Materials Science and Engineering Hernando, Habib Marpongahtun Julianti, Elisa Nuryawan, Arif Amaturrahim, Suci Aisyah Piliang, Averroes Fazlur Rahman Yanhar, Muhammad Rafiq Goei, Ronn Soykeabkaew, Nattakan Saputra, A. Muhammad Afdhal Gea, Saharman |
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Article |
author |
Hernando, Habib Marpongahtun Julianti, Elisa Nuryawan, Arif Amaturrahim, Suci Aisyah Piliang, Averroes Fazlur Rahman Yanhar, Muhammad Rafiq Goei, Ronn Soykeabkaew, Nattakan Saputra, A. Muhammad Afdhal Gea, Saharman |
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Hernando, Habib |
title |
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
title_short |
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
title_full |
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
title_fullStr |
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
title_full_unstemmed |
Impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
title_sort |
impact of glycerol on oil palm trunk starch bioplastics enhanced with citric-acid epoxidized palm oil oligomers |
publishDate |
2024 |
url |
https://hdl.handle.net/10356/181338 |
_version_ |
1816859002807517184 |