Stereoconvergent access to Z-allylborons from E/Z-mixed 1,3-dienes via Cu-guanidine catalysis

• Main Authors: Zhang, Ai, Zhang, Huangfeng, Jin, Tao, Ge, Lin, Ma, Xiaoyan, Tang, Jinghua, Liu, Jinyu, Tan, Choon-Hong, Lee, Richmond, Ge, Yicen
• Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
• Format: Article
• Language: English
• Published: 2025
• Subjects: Chemistry; Protoborylation; Stereoconvergency
• Online Access: https://hdl.handle.net/10356/182257
• Institution: Nanyang Technological University

Merging the stereoisomeric mixture of substrate into a single product through stereospecific transformation is a challenging but higher-order synthetic strategy, which perfectly meets the demand of cost control in the precise chemical production. In this work, the stereoconvergent synthesis of Z-all...