Some organic and organotin reactions of 2-(2'-Dimethylaminoethylimino-methyl) phenols

This thesis describes the synthesis of several new N-(2'-dimethylaminoethyi)arylidene-imines (L) of the formula 2-HOC6H3(X)C(R)=N(CH2)nNR,2 and their reduced products (LH) with the formula of 2-HOC6H3(X)CH(R)NH(CH2)nNR,2 (where X = H, 3-OCH3, 5-Br and 5-N02; R =H and CH3; n = 2 and 3; R' =...

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Bibliographic Details
Main Author: Hu, Hong Juan.
Other Authors: Goh, Ngoh Khang
Format: Theses and Dissertations
Language:English
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10356/20312
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Institution: Nanyang Technological University
Language: English
Description
Summary:This thesis describes the synthesis of several new N-(2'-dimethylaminoethyi)arylidene-imines (L) of the formula 2-HOC6H3(X)C(R)=N(CH2)nNR,2 and their reduced products (LH) with the formula of 2-HOC6H3(X)CH(R)NH(CH2)nNR,2 (where X = H, 3-OCH3, 5-Br and 5-N02; R =H and CH3; n = 2 and 3; R' = CH3 and C2H5). The coordination behaviour towards diphenyltin dichloride and triphenyltin chloride of these newly synthesized Schiff bases, together with their saturated analogues, was also investigated. For the sake of convenience, the work embodied in this thesis is presented in the following chapters.