Rhodium-catalyzed 1,4-addition of triorgano(vinyl)silanes to electron-deficient olefins and application towards the preparation of functionalized organoboron compounds
It was recently discovered in the author’s group that the transmetalation of typically unreactive triorgano(vinyl)silanes could be accomplished with [RhCl(CO)2]2, leading to the development of a rhodium-catalyzed acylation of triorgano(vinyl)silanes with acid anhydrides. Employing a similar transm...
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| 格式: | Theses and Dissertations |
| 語言: | English |
| 出版: |
2010
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| 在線閱讀: | http://hdl.handle.net/10356/20874 |
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