Rhodium-catalyzed 1,4-addition of triorgano(vinyl)silanes to electron-deficient olefins and application towards the preparation of functionalized organoboron compounds

Rhodium-catalyzed 1,4-addition of triorgano(vinyl)silanes to electron-deficient olefins and application towards the preparation of functionalized organoboron compounds

It was recently discovered in the author’s group that the transmetalation of typically unreactive triorgano(vinyl)silanes could be accomplished with [RhCl(CO)2]2, leading to the development of a rhodium-catalyzed acylation of triorgano(vinyl)silanes with acid anhydrides. Employing a similar transm...

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Bibliographic Details
Main Author: Ng, Yu Rui
Other Authors: Koichi Narasaka
Format: Theses and Dissertations
Language:English
Published: 2010
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:http://hdl.handle.net/10356/20874
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Institution: Nanyang Technological University
Language: English

Internet

http://hdl.handle.net/10356/20874

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