Rhodium-catalyzed 1,4-addition of triorgano(vinyl)silanes to electron-deficient olefins and application towards the preparation of functionalized organoboron compounds

• المؤلف الرئيسي: Ng, Yu Rui
• مؤلفون آخرون: Koichi Narasaka
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2010
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/20874

It was recently discovered in the author’s group that the transmetalation of typically unreactive triorgano(vinyl)silanes could be accomplished with [RhCl(CO)2]2, leading to the development of a rhodium-catalyzed acylation of triorgano(vinyl)silanes with acid anhydrides. Employing a similar transm...