Facile synthesis of yolk shell structures : swelling polymer encapsulated gold nanoparticles.

We report a preliminary result on a facile synthesis of Au@[oleic acid]@[polystyrene-poly(acrylic acid)] yolk shell structure using swelling and de-swelling method. The yolk shell structure formed contained a pseudo layer/middle layer is made up of fluid like oleic acid. Using this method, structure...

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Bibliographic Details
Main Author: Chong, Wen Han.
Other Authors: Chen Hongyu
Format: Final Year Project
Language:English
Published: 2010
Subjects:
Online Access:http://hdl.handle.net/10356/39806
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Institution: Nanyang Technological University
Language: English
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Summary:We report a preliminary result on a facile synthesis of Au@[oleic acid]@[polystyrene-poly(acrylic acid)] yolk shell structure using swelling and de-swelling method. The yolk shell structure formed contained a pseudo layer/middle layer is made up of fluid like oleic acid. Using this method, structure morphology control between yolk shell structures and swollen core shell structures were achieved. We proposed that the formation of yolk shell structures is controlled kinetically while swollen core shell structures are thermodynamically controlled.