Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.

Both napthylamine and benzylamine chiral cyclopalladated and cycloplatinated template have been used for monoinsertion of di(phenylethynyl)phenylphosphine ligand into the Pd-C bond of orthopalladated naphthylamine. These insertions proved to be possible under mild reaction conditions and resulted in...

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Main Author: Quek, Sharon Su Ping.
Other Authors: Leung Pak Hing
Format: Final Year Project
Language:English
Published: 2010
Subjects:
Online Access:http://hdl.handle.net/10356/39827
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-398272023-02-28T23:18:03Z Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template. Quek, Sharon Su Ping. Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis Both napthylamine and benzylamine chiral cyclopalladated and cycloplatinated template have been used for monoinsertion of di(phenylethynyl)phenylphosphine ligand into the Pd-C bond of orthopalladated naphthylamine. These insertions proved to be possible under mild reaction conditions and resulted in a series of regioselective complex: including homo- or heterodimetallic compound incorporating the new generated P-chiral center. Among which, the major product produced adopted the R configuration. However, there is an exception to the experiment whereby the expected configuration was not obtained. The coordination chemistry and the stereochemistry of the insertion products and transformation products were deduced by X-Ray crystallography. And the effectiveness of the metal template was discussed. Bachelor of Science in Chemistry and Biological Chemistry 2010-06-04T08:35:34Z 2010-06-04T08:35:34Z 2010 2010 Final Year Project (FYP) http://hdl.handle.net/10356/39827 en 27 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Quek, Sharon Su Ping.
Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
description Both napthylamine and benzylamine chiral cyclopalladated and cycloplatinated template have been used for monoinsertion of di(phenylethynyl)phenylphosphine ligand into the Pd-C bond of orthopalladated naphthylamine. These insertions proved to be possible under mild reaction conditions and resulted in a series of regioselective complex: including homo- or heterodimetallic compound incorporating the new generated P-chiral center. Among which, the major product produced adopted the R configuration. However, there is an exception to the experiment whereby the expected configuration was not obtained. The coordination chemistry and the stereochemistry of the insertion products and transformation products were deduced by X-Ray crystallography. And the effectiveness of the metal template was discussed.
author2 Leung Pak Hing
author_facet Leung Pak Hing
Quek, Sharon Su Ping.
format Final Year Project
author Quek, Sharon Su Ping.
author_sort Quek, Sharon Su Ping.
title Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
title_short Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
title_full Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
title_fullStr Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
title_full_unstemmed Asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the Pd-C bond of orthopalladated naphthylamine promoted by cyclometallated template.
title_sort asymmetric synthesis of p-stereogenic homo- and hetero-bimetallic complexes via monoinsertion of di(phenylethynyl)phenylphosphine into the pd-c bond of orthopalladated naphthylamine promoted by cyclometallated template.
publishDate 2010
url http://hdl.handle.net/10356/39827
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