Selective oxidation of benzyl alcohol over Pd/MnCeOx catalyst
Benzyl alcohol aerobic selective oxidation to benzaldehyde over Pd /MnCeOx was investigated in this study. Method of loading metal catalyst to the support, the composition (structure) of the support, Pd loading amount are 3 important variables in the optimization of the catalyst. Their relationsh...
Saved in:
Main Author: | |
---|---|
Other Authors: | |
Format: | Final Year Project |
Language: | English |
Published: |
2010
|
Subjects: | |
Online Access: | http://hdl.handle.net/10356/39841 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
Summary: | Benzyl alcohol aerobic selective oxidation to benzaldehyde over Pd /MnCeOx was
investigated in this study. Method of loading metal catalyst to the support, the
composition (structure) of the support, Pd loading amount are 3 important variables in the
optimization of the catalyst. Their relationships with catalytic performance were studied
to determine the best combination of these 3 variables, yielding the optimized catalysts.
Results showed that 0.5 wt% Pd on crystalline MnCeOx (10Mn1Ce) and 0.5 wt% Pd on
amorphous MnCeOx (7Mn3Ce) both loaded using microwave (MW) method displayed
best activity and selectivity, with the latter being slightly more generic. Synergistic effect
between MnOx and CeO2 in mixed MnCeOx support was demonstrated. It was also found
that Pd is likely to be the only active species in the catalyst. Physical characterizations
such as X-ray diffraction(XRD) and physisorption were done to study more about how
structural parameters changes when the variables changed and how these parameter
changes affect the catalytic performance. XRD showed that there is poorer pore
distribution in amorphous support compared to crystalline and exact species of crystalline
MnCeOx are CeO2, Mn3O4 and Mn2O3. Other findings include pore size effect was found
to be significant in crystalline support while specific surface area effect significant in
amorphous support and high metal loading tend to cause agglomeration of metal species,
leading to lower activity. |
---|