Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis

• 主要作者: Xu, Xiangya
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Theses and Dissertations
• 語言: English
• 出版: 2011
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Heterocyclic compounds
• 在線閱讀: https://hdl.handle.net/10356/46226

N-heterocyclic carbenes (NHCs) have been extensively investigated and widely used as more efficient ligands. The experimental and theoretical evidences showed that C4 or C5-bound NHCs (aNHCs) are stronger donor ligands than C2-bound NHCs (nNHCs). It is expected that the outstanding strong donor abil...