Asymmetric ligand transformation reactions promoted by cyclometallated complexes

• Main Author: Cheow, Yuen Lin
• Other Authors: Leung Pak Hing
• Format: Theses and Dissertations
• Language: English
• Published: 2012
• Subjects: DRNTU::Science
• Online Access: https://hdl.handle.net/10356/47715
• Institution: Nanyang Technological University

Complex bis(u-chloro)-bis{(R)-1-(dimethylamino)ethyl] naphtyl-C2,N} palladium (II) was found to successfully undergo insertion reactions at the palladium-carbon with the diphenylarsinoprop-1-yne ligand at room temperature which leads to the formation of a new 7-membered metallacyce in the inserted p...