Asymmetric ligand transformation reactions promoted by cyclometallated complexes

• المؤلف الرئيسي: Cheow, Yuen Lin
• مؤلفون آخرون: Leung Pak Hing
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2012
• الموضوعات: DRNTU::Science
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/47715

Complex bis(u-chloro)-bis{(R)-1-(dimethylamino)ethyl] naphtyl-C2,N} palladium (II) was found to successfully undergo insertion reactions at the palladium-carbon with the diphenylarsinoprop-1-yne ligand at room temperature which leads to the formation of a new 7-membered metallacyce in the inserted p...