New strategies for O- and C-glycosylation.

• Main Author: Tan, Hong Yee.
• Other Authors: Liu Xuewei
• Format: Theses and Dissertations
• Language: English
• Published: 2012
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Carbohydrates
• Online Access: http://hdl.handle.net/10356/49504
• Institution: Nanyang Technological University

In part A, we have established an efficient iron-catalyzed decarboxylative C-glycosylation of glycals with β-keto acids via decarboxylative Ferrier rearrangement strategy. This approach provides a wide range of β-keto-functionalized 2,3-unsaturated C-glycosides in moderate to good yields. Good α-sel...