Design and synthesis of ordered periodical mesoporous organosilicas for various applications

Periodical Mesoporous Organosilicas (PMOs) is a new class of solid mesoporous materials that have various applications in many fields such as gas storage, catalysis and sequestration of pollutants etc. Design and synthesize new PMOs for different applications--gas storage and catalysis--are of great...

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Main Author: Guo, Junfei
Other Authors: School of Physical and Mathematical Sciences
Format: Theses and Dissertations
Language:English
Published: 2013
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Online Access:http://hdl.handle.net/10356/53731
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-537312023-02-28T23:36:01Z Design and synthesis of ordered periodical mesoporous organosilicas for various applications Guo, Junfei School of Physical and Mathematical Sciences Zhao Yanli DRNTU::Science Periodical Mesoporous Organosilicas (PMOs) is a new class of solid mesoporous materials that have various applications in many fields such as gas storage, catalysis and sequestration of pollutants etc. Design and synthesize new PMOs for different applications--gas storage and catalysis--are of great importance for both materials research and industry. A novel pyridine urea (PU) precursor ligand was designed, synthesized and successfully incorporated into PMOs. The PU precursor functionalized PMOs was an excellent solid support for catalytic active species like palladium. The PU-PMOs supported palladium catalyst shows outstanding catalytic activity for Suzuki and Sonogashira cross coupling reactions while the PMOs do not exhibit significant adsorption ability for carbon dioxide. Another nitrogen rich ligand (NTT), with many amine and triazole groups was designed and synthesized. This NTT ligand was designed to have rate acceleration ability for copper catalyzed alkyne –azide cycloaddition (CuAAC) reaction to be incorporated into PMOs for carbon dioxide adsorption. Master of Science 2013-06-07T02:37:15Z 2013-06-07T02:37:15Z 2013 2013 Thesis http://hdl.handle.net/10356/53731 en 97 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science
spellingShingle DRNTU::Science
Guo, Junfei
Design and synthesis of ordered periodical mesoporous organosilicas for various applications
description Periodical Mesoporous Organosilicas (PMOs) is a new class of solid mesoporous materials that have various applications in many fields such as gas storage, catalysis and sequestration of pollutants etc. Design and synthesize new PMOs for different applications--gas storage and catalysis--are of great importance for both materials research and industry. A novel pyridine urea (PU) precursor ligand was designed, synthesized and successfully incorporated into PMOs. The PU precursor functionalized PMOs was an excellent solid support for catalytic active species like palladium. The PU-PMOs supported palladium catalyst shows outstanding catalytic activity for Suzuki and Sonogashira cross coupling reactions while the PMOs do not exhibit significant adsorption ability for carbon dioxide. Another nitrogen rich ligand (NTT), with many amine and triazole groups was designed and synthesized. This NTT ligand was designed to have rate acceleration ability for copper catalyzed alkyne –azide cycloaddition (CuAAC) reaction to be incorporated into PMOs for carbon dioxide adsorption.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Guo, Junfei
format Theses and Dissertations
author Guo, Junfei
author_sort Guo, Junfei
title Design and synthesis of ordered periodical mesoporous organosilicas for various applications
title_short Design and synthesis of ordered periodical mesoporous organosilicas for various applications
title_full Design and synthesis of ordered periodical mesoporous organosilicas for various applications
title_fullStr Design and synthesis of ordered periodical mesoporous organosilicas for various applications
title_full_unstemmed Design and synthesis of ordered periodical mesoporous organosilicas for various applications
title_sort design and synthesis of ordered periodical mesoporous organosilicas for various applications
publishDate 2013
url http://hdl.handle.net/10356/53731
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