Part I : Synthesis of azaheterocycles from aryl ketone o-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2h-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via cu(ii)-mediated iminooxygenation of N-H imines with tempo.
Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities.
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| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2013
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| Online Access: | http://hdl.handle.net/10356/54685 |
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| Institution: | Nanyang Technological University |
| Language: | English |