NHC-catalyzed activation of aldehydes for asymmetric reactions

• المؤلف الرئيسي: Chen, Xingkuan
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/59523
• المؤسسة: Nanyang Technological University

My study is mainly focused on the N-heterocyclic carbene catalytic activation of special aldehydes reactions. In this thesis, cis-enals and α-branched indole 3-carboxaldehydes were explored. cis-Enals with carbene could form cis-homoenolate intermediate which offer different stereo selectivities and...