Diyne and bisalkynyl complexes of pentamethylcyclopentadienyliridium

The reductive elimination of [Cp*Ir(CO)(C≡CPh)2] to [Cp*Ir(CO)(PhC≡C-C≡CPh)] has been investigated. This reaction proceeds at an accelerated rates in protic solvents, and the reaction pathway has been examined computationally and experimentally. The effects of substitution at the phenyl ring and of...

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Bibliographic Details
Main Author: Li, Yongjia
Other Authors: Leong Weng Kee
Format: Theses and Dissertations
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/65638
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Institution: Nanyang Technological University
Language: English