Diyne and bisalkynyl complexes of pentamethylcyclopentadienyliridium
The reductive elimination of [Cp*Ir(CO)(C≡CPh)2] to [Cp*Ir(CO)(PhC≡C-C≡CPh)] has been investigated. This reaction proceeds at an accelerated rates in protic solvents, and the reaction pathway has been examined computationally and experimentally. The effects of substitution at the phenyl ring and of...
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| 格式: | Theses and Dissertations |
| 語言: | English |
| 出版: |
2015
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| 在線閱讀: | https://hdl.handle.net/10356/65638 |
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| 機構: | Nanyang Technological University |
| 語言: | English |