Diyne and bisalkynyl complexes of pentamethylcyclopentadienyliridium

• المؤلف الرئيسي: Li, Yongjia
• مؤلفون آخرون: Leong Weng Kee
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/65638

The reductive elimination of [Cp*Ir(CO)(C≡CPh)2] to [Cp*Ir(CO)(PhC≡C-C≡CPh)] has been investigated. This reaction proceeds at an accelerated rates in protic solvents, and the reaction pathway has been examined computationally and experimentally. The effects of substitution at the phenyl ring and of...