Osmium- and ruthenium-antimony carbonyl clusters and rings

• المؤلف الرئيسي: Li, Yingzhou
• مؤلفون آخرون: Leong Weng Kee
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2016
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/65872
• المؤسسة: Nanyang Technological University

The reaction of the lightly stabilized cluster Os3(CO)11(NCCH3) with the hydrostibine SbPh2H afforded the four-membered ring Os3(H)(CO)11(μ-SbPh2). A similar reaction with the distibine Sb2Ph4 gave the analogue Os3(SbPh2)(CO)11(μ-SbPh2), which can be regarded as a metalloligand with the presence of...