Synthesis and Reactivity of Ruthenium-Antimony Carbonyl Clusters

• Main Authors: Li, Ying-Zhou, Ganguly, Rakesh, Leong, Weng Kee, Liu, Yang
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2015
• 主題: DRNTU::Science::Chemistry::Organic chemistry
• 在線閱讀: https://hdl.handle.net/10356/103652; http://hdl.handle.net/10220/38790

The reaction of Na[HRu3(CO)11] (2) with SbPh2Cl in dry tetrahydrofuran (THF) afforded the cluster Ru3(CO)10(μ-H)(μ-SbPh2) (3); in dry dichloromethane (DCM), the six-membered ring Ru6(CO)20(μ-H)2(μ-SbPh2)2 (4) was obtained instead. The trimethylamine N-oxide (TMNO) activated reaction of Ru3(CO)12 (1)...