The metallostibine Os2(CO)8(μ-SbPh) : a versatile donor precursor for antimony-containing heterometallic clusters

The metallostibine Os2(CO)8(μ-SbPh) : a versatile donor precursor for antimony-containing heterometallic clusters

The metallostibine Os2(CO)8(μ-SbPh), 2, acts as a good two-electron donor ligand, reacting readily with Group 8 metal carbonyls to give heterometallic clusters. Specifically, it undergoes ligand substitution reaction with Fe2(CO)9, Os3(CO)11(CH3CN), or Os3(CO)10(CH3CN)2 to afford Os2Fe(CO)12(μ3-SbPh...

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Bibliographic Details
Main Authors: Li, Ying-Zhou, Ganguly, Rakesh, Rajaratnam, Deborah Roshni, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2019
Subjects:
Metallostibine
DRNTU::Science::Chemistry
Metalloligand
Online Access:https://hdl.handle.net/10356/86018
http://hdl.handle.net/10220/48269
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/86018
http://hdl.handle.net/10220/48269

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