The metallostibine Os2(CO)8(μ-SbPh) : a versatile donor precursor for antimony-containing heterometallic clusters

• Main Authors: Li, Ying-Zhou, Ganguly, Rakesh, Rajaratnam, Deborah Roshni, Leong, Weng Kee
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2019
• Subjects: Metallostibine; DRNTU::Science::Chemistry; Metalloligand
• Online Access: https://hdl.handle.net/10356/86018; http://hdl.handle.net/10220/48269
• Institution: Nanyang Technological University

The metallostibine Os2(CO)8(μ-SbPh), 2, acts as a good two-electron donor ligand, reacting readily with Group 8 metal carbonyls to give heterometallic clusters. Specifically, it undergoes ligand substitution reaction with Fe2(CO)9, Os3(CO)11(CH3CN), or Os3(CO)10(CH3CN)2 to afford Os2Fe(CO)12(μ3-SbPh...