Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films
Vanadium dioxide (VO2) is a promising candidate for smart windows as it exhibits a reversible metal to insulator (MIT) phase transition. However, the phase transition temperature (τc) of pure VO2 occurs at 68oC which is comparatively higher than room temperature (25oC). Hence, the practical applicat...
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sg-ntu-dr.10356-673062023-03-04T15:43:30Z Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films Tan, Nigel Chew Shun Long Yi School of Materials Science and Engineering Singapore National Research Foundation under the CREATE programme Wang Ning DRNTU::Engineering DRNTU::Science Vanadium dioxide (VO2) is a promising candidate for smart windows as it exhibits a reversible metal to insulator (MIT) phase transition. However, the phase transition temperature (τc) of pure VO2 occurs at 68oC which is comparatively higher than room temperature (25oC). Hence, the practical application is limited due to its high τc and low integrated visible transmission (Tlum). Thus, appropriate dopant is required to depress τc to ambient temperature. As a result, Lanthanum, a rare earth element was introduced to modify the optical properties of VO2. Sol-gel technique was utilized to fabricate La doped VO2 thin films. Subsequently, TEM and EDX characterizations were used to verify La doping while UV-Vis-NIR spectroscopy was used to monitor τc. La doping reduces τc of VO2 below the 4 at. % doping level effectively, at a τc reduction rate of -1.1 °C/at.%. Furthermore, the band gap (Eg) decreased progressively along with the addition of La dopants below the 3 at.% doping level. The optimum value for La doped VO2 thin films was found to be 4 at.% doping level with cooling τc of 49.2oC and the combination of integrated visible transmission (Tlum) and solar modulating ability (ΔTsol) were increased to 50% and 10.3% respectively. This result showed superior Tlum and ΔTsol as compared with undoped VO2 thin films. Bachelor of Engineering (Materials Engineering) 2016-05-15T01:23:45Z 2016-05-15T01:23:45Z 2016 Final Year Project (FYP) http://hdl.handle.net/10356/67306 en Nanyang Technological University 49 p. application/pdf |
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DRNTU::Engineering DRNTU::Science Tan, Nigel Chew Shun Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
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Vanadium dioxide (VO2) is a promising candidate for smart windows as it exhibits a reversible metal to insulator (MIT) phase transition. However, the phase transition temperature (τc) of pure VO2 occurs at 68oC which is comparatively higher than room temperature (25oC). Hence, the practical application is limited due to its high τc and low integrated visible transmission (Tlum). Thus, appropriate dopant is required to depress τc to ambient temperature. As a result, Lanthanum, a rare earth element was introduced to modify the optical properties of VO2. Sol-gel technique was utilized to fabricate La doped VO2 thin films. Subsequently, TEM and EDX characterizations were used to verify La doping while UV-Vis-NIR spectroscopy was used to monitor τc. La doping reduces τc of VO2 below the 4 at. % doping level effectively, at a τc reduction rate of -1.1 °C/at.%. Furthermore, the band gap (Eg) decreased progressively along with the addition of La dopants below the 3 at.% doping level. The optimum value for La doped VO2 thin films was found to be 4 at.% doping level with cooling τc of 49.2oC and the combination of integrated visible transmission (Tlum) and solar modulating ability (ΔTsol) were increased to 50% and 10.3% respectively. This result showed superior Tlum and ΔTsol as compared with undoped VO2 thin films. |
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Long Yi |
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Long Yi Tan, Nigel Chew Shun |
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Final Year Project |
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Tan, Nigel Chew Shun |
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Tan, Nigel Chew Shun |
title |
Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
title_short |
Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
title_full |
Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
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Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
title_full_unstemmed |
Effect of lanthanum doping on modulating thermochromic properties of VO2 thin films = Thermochromic properties of la doped VO2 thin films |
title_sort |
effect of lanthanum doping on modulating thermochromic properties of vo2 thin films = thermochromic properties of la doped vo2 thin films |
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2016 |
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http://hdl.handle.net/10356/67306 |
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1759854176989347840 |