Geminal dianionic complexes and their corresponding carbenoids for small molecule activation

• 主要作者: Ho, Samuel Ying Fu
• 其他作者: So Cheuk Wai
• 格式: Theses and Dissertations
• 語言: English
• 出版: 2016
• 主題: DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis
• 在線閱讀: http://hdl.handle.net/10356/68863
• 機構: Nanyang Technological University

The thesis describes the synthesis of metal carbenoids and their application towards small molecule activation and the catalytic reduction of CO2 with borane. Chapter 1 describes the synthesis of a novel unsymmetric phosphonium-stabilized methane ligand, the monoanionic and dianionic lithium and ma...