N-heterocyclic germylene-metal adducts

• المؤلف الرئيسي: Leong, Bi Xiang
• مؤلفون آخرون: So Cheuk Wai
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2016
• الموضوعات: DRNTU::Science::Chemistry::Inorganic chemistry::Metals
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/68970
• المؤسسة: Nanyang Technological University

The N-heterocyclic chlorogermylene and chlorostannylene of composition [L"E" ̈Cl] (E = Ge, Sn; L = PhC(NtBu)2) is a Lewis bases due to the stabilization of the metal centres’ empty orbitals being stabilized by the lone pair electrons on the nitrogen atom of the ligand. Further stabilizati...