Synthesis and reactivity of electron-deficient phosphorus(III) compounds

• Main Author: Dordevic, Nemanja
• Other Authors: Rei Kinjo
• Format: Theses and Dissertations
• Language: English
• Published: 2017
• Subjects: DRNTU::Science::Chemistry::Inorganic chemistry::Non-metals
• Online Access: http://hdl.handle.net/10356/72751
• Institution: Nanyang Technological University

Our work reflects efforts to increase the Lewis acidity of two-coordinate phosphorus(III)-based compounds for the purpose of small molecule activation. In this view, we tuned the electronic properties of phosphenium ions by increasing their overall positive charge and by varying the extent of π-dona...