Development of new reactions and reagents in carbene-catalyzed addition of carbon and nitrogen nucleophiles to unsaturated acyl azolium intermediates

• المؤلف الرئيسي: Wu, Xingxing
• مؤلفون آخرون: Robin Chi Yonggui
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2017
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/72774
• المؤسسة: Nanyang Technological University

This thesis focuses on development of efficient protocols for access to advanced complex molecules enabled by N-heterocyclic carbene (NHC) catalyzed LUMO activation of enal or its ester derivatives, and discovery of polyhalide as simple organic oxidant for oxidative carbene catalysis. It contains fi...