Part I. Synthesis of chiral 3-substituted indanones via transition-metal-catalyzed reductive heck reaction. Part II. Tert-butyl peroxybenzoate promoted oxidative coupling between heteroarenes and alkanes
A new approach to chiral 3-substituted indanones via palladium-catalyzed reductive Heck reaction with excellent yields (>80%) and enantioselectivities (>90% ee) had been developed. Substrates with ortho-, para- substitution, or with electron-donating, electron-withdrawing groups on the phenyl...
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| 格式: | Thesis-Doctor of Philosophy |
| 語言: | English |
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Nanyang Technological University
2018
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| 主題: | |
| 在線閱讀: | http://hdl.handle.net/10356/73253 |
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