Light-operated rotaxanes on graphene

Rotaxanes as one species of mechanically interlocked molecular architecture are of a lot of concern today. Moreover, monolayer graphene which has remarkable electronic, optical and mechanical properties also attracts large amount of research interest. This research aims to combine the ro...

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Bibliographic Details
Main Author: Li, Xing
Other Authors: Zhao Yanli
Format: Student Research Poster
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/79525
http://hdl.handle.net/10220/8939
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Institution: Nanyang Technological University
Language: English
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Summary:Rotaxanes as one species of mechanically interlocked molecular architecture are of a lot of concern today. Moreover, monolayer graphene which has remarkable electronic, optical and mechanical properties also attracts large amount of research interest. This research aims to combine the rotaxanes which are the macrocycle interlocked dumbbell shaped onto the monolayer graphene with a structure of two-dimesional hexagonal carbon lattice, and create an optical-controlled molecular machine. The new properties are tested and further applied into the areas such as molecular switches, molecular logic gates and molecular memories. [2nd Award]