The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex

Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally...

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Main Authors:	Mak, Garvin Kar Hang, Fan, Wai Yip, Sridevi, Venugopal Shanmugham, Leong, Weng Kee
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	Chemistry and Biological Chemistry
Online Access:	https://hdl.handle.net/10356/79752 http://hdl.handle.net/10220/18612
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-79752
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spelling	sg-ntu-dr.10356-797522023-02-28T19:30:02Z The reaction of [CpIrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee School of Physical and Mathematical Sciences Chemistry and Biological Chemistry Reaction of the dimeric species [CpIrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally. MOE (Min. of Education, S’pore) Accepted version 2014-01-20T02:08:25Z 2019-12-06T13:33:23Z 2014-01-20T02:08:25Z 2019-12-06T13:33:23Z 2013 2013 Journal Article Mak, K. H. G., Fan, W. Y., Sridevi, V. S., & Leong, W. K. (2013). The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex. Journal of Organometallic Chemistry, 739, 52-56. 0022-328X https://hdl.handle.net/10356/79752 http://hdl.handle.net/10220/18612 10.1016/j.jorganchem.2013.04.037 en Journal of Organometallic Chemistry © 2013 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2013.04.037]. 5 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	Chemistry and Biological Chemistry
spellingShingle	Chemistry and Biological Chemistry Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
description	Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee
format	Article
author	Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee
author_sort	Mak, Garvin Kar Hang
title	The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
title_short	The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
title_full	The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
title_fullStr	The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
title_full_unstemmed	The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
title_sort	reaction of [cp*ircl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
publishDate	2014
url	https://hdl.handle.net/10356/79752 http://hdl.handle.net/10220/18612
_version_	1759855621346164736

The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex

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