Hierarchical ZnO/Bi2O3 nanostructures : synthesis, characterization, and electron-beam modification

Two types of ZnO/Bi2O3 nanonecklace heterostructures were fabricated using the vapor-phase transport (VPT) method for the first time. These hierarchical structures were well characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and transmission electron micro...

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Bibliographic Details
Main Authors: Ling, Bo, Sun, Xiaowei, Shen, Yiqiang, Dong, Zhili
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2012
Subjects:
Online Access:https://hdl.handle.net/10356/79887
http://hdl.handle.net/10220/8828
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Institution: Nanyang Technological University
Language: English
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Summary:Two types of ZnO/Bi2O3 nanonecklace heterostructures were fabricated using the vapor-phase transport (VPT) method for the first time. These hierarchical structures were well characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS) attached. The growth mechanism of the novel structures were proposed based on these characterizations. Electron-beam irradiation was found to be a powerful and controllable tool in further tailoring such ZnO/Bi2O3 nanonecklace heterostructures. In addition, photoluminescence (PL) emission from the hierarchical nanostructures showed enhancement comparing to the pure Bi2O3 powder.