Formal hydration of non-activated terminal olefins using tandem catalysts

The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%.

Saved in:
Bibliographic Details
Main Authors: Yang, Yongsheng, Guo, Jiayi, Ng, Huimin, Chen, Zhiyong, Teo, Peili
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2016
Subjects:
Online Access:https://hdl.handle.net/10356/81016
http://hdl.handle.net/10220/40662
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-81016
record_format dspace
spelling sg-ntu-dr.10356-810162023-07-14T15:44:41Z Formal hydration of non-activated terminal olefins using tandem catalysts Yang, Yongsheng Guo, Jiayi Ng, Huimin Chen, Zhiyong Teo, Peili School of Materials Science & Engineering Secondary alcohols The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%. ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2016-06-13T04:06:27Z 2019-12-06T14:19:38Z 2016-06-13T04:06:27Z 2019-12-06T14:19:38Z 2014 2014 Journal Article Yang, Y., Guo, J., Ng, H., Chen, Z., & Teo, P. (2014). Formal hydration of non-activated terminal olefins using tandem catalysts. Chemical Communications, 50(20), 2608-2611. 1359-7345 https://hdl.handle.net/10356/81016 http://hdl.handle.net/10220/40662 10.1039/c3cc48810a 194405 en Chemical Communications © 2014 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Communications, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/ 10.1039/c3cc48810a]. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Secondary alcohols
spellingShingle Secondary alcohols
Yang, Yongsheng
Guo, Jiayi
Ng, Huimin
Chen, Zhiyong
Teo, Peili
Formal hydration of non-activated terminal olefins using tandem catalysts
description The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Yang, Yongsheng
Guo, Jiayi
Ng, Huimin
Chen, Zhiyong
Teo, Peili
format Article
author Yang, Yongsheng
Guo, Jiayi
Ng, Huimin
Chen, Zhiyong
Teo, Peili
author_sort Yang, Yongsheng
title Formal hydration of non-activated terminal olefins using tandem catalysts
title_short Formal hydration of non-activated terminal olefins using tandem catalysts
title_full Formal hydration of non-activated terminal olefins using tandem catalysts
title_fullStr Formal hydration of non-activated terminal olefins using tandem catalysts
title_full_unstemmed Formal hydration of non-activated terminal olefins using tandem catalysts
title_sort formal hydration of non-activated terminal olefins using tandem catalysts
publishDate 2016
url https://hdl.handle.net/10356/81016
http://hdl.handle.net/10220/40662
_version_ 1772827629577043968