Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation

Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation

A Pd/Ir dual metal tandem catalyst system was found to be active in catalyzing the one-pot, two-step formal hydroamination of unbiased olefins such as 1-dodecene with an ammonia source to give branched primary amines in high yields of >85 % by using only 1 mol-% of the Ir catalyst. This is the fi...

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Main Authors: Yang, Yongsheng, Wong, Nurul Imma, Teo, Peili
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2016
Subjects:
Hydroamination
Amines
Synthetic methods
Homogeneous catalysis
Alkenes
Online Access:https://hdl.handle.net/10356/81329
http://hdl.handle.net/10220/40729
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-813292023-07-14T15:45:19Z Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation Yang, Yongsheng Wong, Nurul Imma Teo, Peili School of Materials Science & Engineering Hydroamination Amines Synthetic methods Homogeneous catalysis Alkenes A Pd/Ir dual metal tandem catalyst system was found to be active in catalyzing the one-pot, two-step formal hydroamination of unbiased olefins such as 1-dodecene with an ammonia source to give branched primary amines in high yields of >85 % by using only 1 mol-% of the Ir catalyst. This is the first report of the formal one-pot intermolecular hydroamination of olefins to obtain primary amines. ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2016-06-21T06:42:28Z 2019-12-06T14:28:33Z 2016-06-21T06:42:28Z 2019-12-06T14:28:33Z 2015 2015 Journal Article Yang, Y., Wong, N. I. & Teo, P. (2015). Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation. European Journal of Organic Chemistry, 2015(6), 1207-1210. 1434-193X https://hdl.handle.net/10356/81329 http://hdl.handle.net/10220/40729 10.1002/ejoc.201403654 194815 en European Journal of Organic Chemistry © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by European Journal of Organic Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1002/ejoc.201403654]. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Hydroamination
Amines
Synthetic methods
Homogeneous catalysis
Alkenes
spellingShingle Hydroamination
Amines
Synthetic methods
Homogeneous catalysis
Alkenes
Yang, Yongsheng
Wong, Nurul Imma
Teo, Peili
Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
description A Pd/Ir dual metal tandem catalyst system was found to be active in catalyzing the one-pot, two-step formal hydroamination of unbiased olefins such as 1-dodecene with an ammonia source to give branched primary amines in high yields of >85 % by using only 1 mol-% of the Ir catalyst. This is the first report of the formal one-pot intermolecular hydroamination of olefins to obtain primary amines.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Yang, Yongsheng
Wong, Nurul Imma
Teo, Peili
format Article
author Yang, Yongsheng
Wong, Nurul Imma
Teo, Peili
author_sort Yang, Yongsheng
title Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
title_short Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
title_full Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
title_fullStr Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
title_full_unstemmed Formal Intermolecular Hydroamination of Unbiased Olefins for Primary Amine Formation
title_sort formal intermolecular hydroamination of unbiased olefins for primary amine formation
publishDate 2016
url https://hdl.handle.net/10356/81329
http://hdl.handle.net/10220/40729
_version_ 1772828761028296704

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