An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural
An ammonium resin (PBnNH3Cl) was used as a single catalyst for the glucose and polysaccharide dehydration to 5-hydroxymethylfurfural (HMF) in high selectivity (>80%) in a DMSO or biphasic reaction system. The isomerization mechanism was also studied by using the DFT computational method.
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sg-ntu-dr.10356-819742020-06-01T10:13:31Z An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural Cao, Xueqin Teong, Siew Ping Wu, Di Yi, Guangshun Su, Haibin Zhang, Yugen School of Materials Science & Engineering An ammonium resin (PBnNH3Cl) was used as a single catalyst for the glucose and polysaccharide dehydration to 5-hydroxymethylfurfural (HMF) in high selectivity (>80%) in a DMSO or biphasic reaction system. The isomerization mechanism was also studied by using the DFT computational method. ASTAR (Agency for Sci., Tech. and Research, S’pore) 2016-08-03T08:51:44Z 2019-12-06T14:44:03Z 2016-08-03T08:51:44Z 2019-12-06T14:44:03Z 2015 Journal Article Cao, X., Teong, S. P., Wu, D., Yi, G., Su, H., & Zhang, Y. (2015). An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural. Green Chem., 17(4), 2348-2352. https://hdl.handle.net/10356/81974 http://hdl.handle.net/10220/41048 10.1039/C4GC02488E en Green Chemistry © 2015 The Royal Society of Chemistry. 5 p. |
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An ammonium resin (PBnNH3Cl) was used as a single catalyst for the glucose and polysaccharide dehydration to 5-hydroxymethylfurfural (HMF) in high selectivity (>80%) in a DMSO or biphasic reaction system. The isomerization mechanism was also studied by using the DFT computational method. |
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School of Materials Science & Engineering |
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School of Materials Science & Engineering Cao, Xueqin Teong, Siew Ping Wu, Di Yi, Guangshun Su, Haibin Zhang, Yugen |
| format |
Article |
| author |
Cao, Xueqin Teong, Siew Ping Wu, Di Yi, Guangshun Su, Haibin Zhang, Yugen |
| spellingShingle |
Cao, Xueqin Teong, Siew Ping Wu, Di Yi, Guangshun Su, Haibin Zhang, Yugen An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| author_sort |
Cao, Xueqin |
| title |
An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| title_short |
An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| title_full |
An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| title_fullStr |
An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| title_full_unstemmed |
An enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| title_sort |
enzyme mimic ammonium polymer as a single catalyst for glucose dehydration to 5-hydroxymethylfurfural |
| publishDate |
2016 |
| url |
https://hdl.handle.net/10356/81974 http://hdl.handle.net/10220/41048 |
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1681057494439297024 |