Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device
Fiber‐based power sources are receiving interest in terms of application in wearable electronic devices. Herein, fiber‐shaped all‐solid‐state asymmetric energy storage devices are fabricated based on a partially nitridized NiCo2O4 hybrid nanostructures on graphite fibers (GFs). The surface nitridati...
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sg-ntu-dr.10356-824962023-02-28T20:06:24Z Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device Hao, Pin Tan, Hua Liu, Zhihe Chao, Dongliang Jia, Dedong Sang, Yuanhua Liu, Hong Fan, Hong Jin School of Physical and Mathematical Sciences Fiber-based Power Source Flexible Energy Storage DRNTU::Science::Physics Fiber‐based power sources are receiving interest in terms of application in wearable electronic devices. Herein, fiber‐shaped all‐solid‐state asymmetric energy storage devices are fabricated based on a partially nitridized NiCo2O4 hybrid nanostructures on graphite fibers (GFs). The surface nitridation leads to a 3D “pearled‐veil” network structure, in which Ni–Co–N nanospheres are mounted on NiCo2O4 nanosheets' electrode. It is demonstrated that the hybrid materials are more potent than the pure NiCo2O4 in energy storage applications due to a cooperative effect between the constituents. The Ni–Co–N segments augment the pristine oxide nanosheets by enhancing both capacity and rate performance (a specific capacity of 384.75 mAh g−1 at 4 A g−1, and a capacity retention of 86.5% as the current is increased to 20 A g−1). The whole material system has a metallic conductivity that renders high‐rate charge and discharge, and an extremely soft feature, so that it can wrap around arbitrary‐shaped holders. All‐solid‐state asymmetric device is fabricated using Ni–Co–N/NiCo2O4/GFs and carbon nanotubes/GFs as the electrodes. The flexible device delivers outstanding performance compared to most oxide‐based full devices. These structured hybrid materials may find applications in miniaturized foldable energy devices. 2019-06-21T01:59:01Z 2019-12-06T14:56:48Z 2019-06-21T01:59:01Z 2019-12-06T14:56:48Z 2018 Journal Article Tan, H., Liu, Z., Chao, D., Hao, P., Jia, D., Sang, Y., . . . Fan, H. J. (2018). Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device. Advanced Energy Materials, 8(21), 1800685-. doi:10.1002/aenm.201800685 1614-6832 https://hdl.handle.net/10356/82496 http://hdl.handle.net/10220/48894 10.1002/aenm.201800685 en Advanced Energy Materials 10.21979/N9/EKBRR5 © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Tan, H., Liu, Z., Chao, D., Hao, P., Jia, D., Sang, Y., . . . Fan, H. J. (2018). Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device. Advanced Energy Materials, 8(21), 1800685-, which has been published in final form at http://dx.doi.org/10.1002/aenm.201800685. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. 20 p. application/pdf |
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Fiber-based Power Source Flexible Energy Storage DRNTU::Science::Physics Hao, Pin Tan, Hua Liu, Zhihe Chao, Dongliang Jia, Dedong Sang, Yuanhua Liu, Hong Fan, Hong Jin Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
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Fiber‐based power sources are receiving interest in terms of application in wearable electronic devices. Herein, fiber‐shaped all‐solid‐state asymmetric energy storage devices are fabricated based on a partially nitridized NiCo2O4 hybrid nanostructures on graphite fibers (GFs). The surface nitridation leads to a 3D “pearled‐veil” network structure, in which Ni–Co–N nanospheres are mounted on NiCo2O4 nanosheets' electrode. It is demonstrated that the hybrid materials are more potent than the pure NiCo2O4 in energy storage applications due to a cooperative effect between the constituents. The Ni–Co–N segments augment the pristine oxide nanosheets by enhancing both capacity and rate performance (a specific capacity of 384.75 mAh g−1 at 4 A g−1, and a capacity retention of 86.5% as the current is increased to 20 A g−1). The whole material system has a metallic conductivity that renders high‐rate charge and discharge, and an extremely soft feature, so that it can wrap around arbitrary‐shaped holders. All‐solid‐state asymmetric device is fabricated using Ni–Co–N/NiCo2O4/GFs and carbon nanotubes/GFs as the electrodes. The flexible device delivers outstanding performance compared to most oxide‐based full devices. These structured hybrid materials may find applications in miniaturized foldable energy devices. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Hao, Pin Tan, Hua Liu, Zhihe Chao, Dongliang Jia, Dedong Sang, Yuanhua Liu, Hong Fan, Hong Jin |
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Hao, Pin Tan, Hua Liu, Zhihe Chao, Dongliang Jia, Dedong Sang, Yuanhua Liu, Hong Fan, Hong Jin |
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Hao, Pin |
title |
Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
title_short |
Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
title_full |
Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
title_fullStr |
Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
title_full_unstemmed |
Partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
title_sort |
partial nitridation-induced electrochemistry enhancement of ternary oxide nanosheets for fiber energy storage device |
publishDate |
2019 |
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https://hdl.handle.net/10356/82496 http://hdl.handle.net/10220/48894 |
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1759856591001092096 |