Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas

We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized 11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by 12 polarized photoinduced absorption measurements, probing mid-IR po...

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Main Authors: Wang, Zilong, Zhao, Jun, Frank, Bettina, Ran, Qiandong, Adamo, Giorgio, Giessen, Harald, Soci, Cesare
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2016
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Online Access:https://hdl.handle.net/10356/82772
http://hdl.handle.net/10220/40345
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-827722023-02-28T19:30:26Z Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas Wang, Zilong Zhao, Jun Frank, Bettina Ran, Qiandong Adamo, Giorgio Giessen, Harald Soci, Cesare School of Physical and Mathematical Sciences Centre for Disruptive Photonic Technologies (CDPT) conjugated polymer Localized surface plasmons IR nanoantennas polarons We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized 11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by 12 polarized photoinduced absorption measurements, probing mid-IR polaron transitions, and infrared-active vibrational modes of 13 the polymer, which directly gauge the density of photogenerated charge carriers. This work proves the possibility of tuning the 14 polaronic properties of organic semiconductors with plasmonic nanostructures. MOE (Min. of Education, S’pore) Accepted version 2016-03-30T07:31:59Z 2019-12-06T15:05:16Z 2016-03-30T07:31:59Z 2019-12-06T15:05:16Z 2015 Journal Article Wang, Z., Zhao, J., Frank, B., Ran, Q., Adamo, G., Giessen, H., et al. (2015). Plasmon–polaron coupling in conjugated polymer on infrared nanoantennas. Nano Letters, 15(8), 5382-5387. 1530-6984 https://hdl.handle.net/10356/82772 http://hdl.handle.net/10220/40345 10.1021/acs.nanolett.5b01760 en Nano Letters © 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Nano Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.nanolett.5b01760]. 6 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic conjugated polymer
Localized surface plasmons
IR nanoantennas
polarons
spellingShingle conjugated polymer
Localized surface plasmons
IR nanoantennas
polarons
Wang, Zilong
Zhao, Jun
Frank, Bettina
Ran, Qiandong
Adamo, Giorgio
Giessen, Harald
Soci, Cesare
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
description We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized 11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by 12 polarized photoinduced absorption measurements, probing mid-IR polaron transitions, and infrared-active vibrational modes of 13 the polymer, which directly gauge the density of photogenerated charge carriers. This work proves the possibility of tuning the 14 polaronic properties of organic semiconductors with plasmonic nanostructures.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Zilong
Zhao, Jun
Frank, Bettina
Ran, Qiandong
Adamo, Giorgio
Giessen, Harald
Soci, Cesare
format Article
author Wang, Zilong
Zhao, Jun
Frank, Bettina
Ran, Qiandong
Adamo, Giorgio
Giessen, Harald
Soci, Cesare
author_sort Wang, Zilong
title Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
title_short Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
title_full Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
title_fullStr Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
title_full_unstemmed Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
title_sort plasmon–polaron coupling in conjugated polymer on infrared nanoantennas
publishDate 2016
url https://hdl.handle.net/10356/82772
http://hdl.handle.net/10220/40345
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