Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas
We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized 11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by 12 polarized photoinduced absorption measurements, probing mid-IR po...
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sg-ntu-dr.10356-827722023-02-28T19:30:26Z Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas Wang, Zilong Zhao, Jun Frank, Bettina Ran, Qiandong Adamo, Giorgio Giessen, Harald Soci, Cesare School of Physical and Mathematical Sciences Centre for Disruptive Photonic Technologies (CDPT) conjugated polymer Localized surface plasmons IR nanoantennas polarons We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized 11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by 12 polarized photoinduced absorption measurements, probing mid-IR polaron transitions, and infrared-active vibrational modes of 13 the polymer, which directly gauge the density of photogenerated charge carriers. This work proves the possibility of tuning the 14 polaronic properties of organic semiconductors with plasmonic nanostructures. MOE (Min. of Education, S’pore) Accepted version 2016-03-30T07:31:59Z 2019-12-06T15:05:16Z 2016-03-30T07:31:59Z 2019-12-06T15:05:16Z 2015 Journal Article Wang, Z., Zhao, J., Frank, B., Ran, Q., Adamo, G., Giessen, H., et al. (2015). Plasmon–polaron coupling in conjugated polymer on infrared nanoantennas. Nano Letters, 15(8), 5382-5387. 1530-6984 https://hdl.handle.net/10356/82772 http://hdl.handle.net/10220/40345 10.1021/acs.nanolett.5b01760 en Nano Letters © 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Nano Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.nanolett.5b01760]. 6 p. application/pdf |
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conjugated polymer Localized surface plasmons IR nanoantennas polarons |
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conjugated polymer Localized surface plasmons IR nanoantennas polarons Wang, Zilong Zhao, Jun Frank, Bettina Ran, Qiandong Adamo, Giorgio Giessen, Harald Soci, Cesare Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
description |
We propose and demonstrate a novel type of coupling between polarons in a conjugated polymer and localized
11 surface plasmons in infrared (IR) nanoantennas. The near-field interaction between plasmons and polarons is revealed by
12 polarized photoinduced absorption measurements, probing mid-IR polaron transitions, and infrared-active vibrational modes of
13 the polymer, which directly gauge the density of photogenerated charge carriers. This work proves the possibility of tuning the
14 polaronic properties of organic semiconductors with plasmonic nanostructures. |
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School of Physical and Mathematical Sciences |
author_facet |
School of Physical and Mathematical Sciences Wang, Zilong Zhao, Jun Frank, Bettina Ran, Qiandong Adamo, Giorgio Giessen, Harald Soci, Cesare |
format |
Article |
author |
Wang, Zilong Zhao, Jun Frank, Bettina Ran, Qiandong Adamo, Giorgio Giessen, Harald Soci, Cesare |
author_sort |
Wang, Zilong |
title |
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
title_short |
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
title_full |
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
title_fullStr |
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
title_full_unstemmed |
Plasmon–Polaron Coupling in Conjugated Polymer on Infrared Nanoantennas |
title_sort |
plasmon–polaron coupling in conjugated polymer on infrared nanoantennas |
publishDate |
2016 |
url |
https://hdl.handle.net/10356/82772 http://hdl.handle.net/10220/40345 |
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1759854250969530368 |