Part I α,β-dehydrogenation of carbonyl compounds via selenium reagents elimination Part II Indium catalyzed cyclization reaction of acrylate

In in first part, selenium conducted elimination reaction of thioesters was discussed. This is a two-step one-pot reaction, which firstly give an alpha selenium substitute of thioesters, then oxidize the selenium intermediate gives an elimination reaction, which lead to the α,β-unsaturated thioester...

Full description

Saved in:
Bibliographic Details
Main Author: Zhang, Qiuchi
Other Authors: Li Tianhu
Format: Theses and Dissertations
Language:English
Published: 2019
Subjects:
Online Access:https://hdl.handle.net/10356/83381
http://hdl.handle.net/10220/47601
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:In in first part, selenium conducted elimination reaction of thioesters was discussed. This is a two-step one-pot reaction, which firstly give an alpha selenium substitute of thioesters, then oxidize the selenium intermediate gives an elimination reaction, which lead to the α,β-unsaturated thioester as the product. In in second part, an In(III)-TMSBr-catalyzed aryldihydronaphthalene derivatives synthesis method is discussed, the indium catalyst makes the aryl alkyne react with two molecules of acrylate and gives an aryldihydronaphthalene derivative as the product.