Fluctuation solution theory of pure fluids

• Main Authors: Ploetz, Elizabeth A., Smith, Paul E., Pallewela, Gayani Nadeera
• Other Authors: Energy Research Institute @NTU
• Format: Article
• Language: English
• Published: 2017
• Subjects: Particle fluctuations; Phase diagrams
• Online Access: https://hdl.handle.net/10356/83457; http://hdl.handle.net/10220/42592
• Institution: Nanyang Technological University

Fluctuation Solution Theory (FST) provides an alternative view of fluid thermodynamics in terms of pair fluctuations in the particle number and excess energy observed for an equivalent open system. Here we extend the FST approach to provide a series of triplet and quadruplet particle and excess ener...