Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance
Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a hig...
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sg-ntu-dr.10356-838852022-02-16T16:30:20Z Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance Chao, Dongliang Zhu, Changrong Yang, Peihua Xia, Xinhui Liu, Jilei Wang, Jin Fan, Xiaofeng Savilov, Serguei V. Lin, Jianyi Fan, Hong Jin Shen, Ze Xiang School of Physical and Mathematical Sciences Energy Research Institute @ NTU (ERI@N) Reaction Kinetics and Dynamics Batteries Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nanostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis. The graphene foam supported tin(II) sulfide nanoarray anode delivers a high reversible capacity of ∼1,100 mAh g−1 at 30 mA g−1 and ∼420 mAh g−1 at 30 A g−1, which even outperforms its lithium-ion storage performance. The surface-dominated redox reaction rendered by our tailored ultrathin tin(II) sulfide nanostructures may also work in other layered materials for high-performance sodium-ion storage. MOE (Min. of Education, S’pore) Published version 2017-07-14T05:32:59Z 2019-12-06T15:33:53Z 2017-07-14T05:32:59Z 2019-12-06T15:33:53Z 2016 Journal Article Chao, D., Zhu, C., Yang, P., Xia, X., Liu, J., Wang, J., et al. (2016). Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance. Nature Communications, 7, 12122-. 2041-1723 https://hdl.handle.net/10356/83885 http://hdl.handle.net/10220/42866 10.1038/ncomms12122 27358085 en Nature Communications © 2016 The Author(s). This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ 8 p. application/pdf |
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Reaction Kinetics and Dynamics Batteries |
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Reaction Kinetics and Dynamics Batteries Chao, Dongliang Zhu, Changrong Yang, Peihua Xia, Xinhui Liu, Jilei Wang, Jin Fan, Xiaofeng Savilov, Serguei V. Lin, Jianyi Fan, Hong Jin Shen, Ze Xiang Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| description |
Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nanostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis. The graphene foam supported tin(II) sulfide nanoarray anode delivers a high reversible capacity of ∼1,100 mAh g−1 at 30 mA g−1 and ∼420 mAh g−1 at 30 A g−1, which even outperforms its lithium-ion storage performance. The surface-dominated redox reaction rendered by our tailored ultrathin tin(II) sulfide nanostructures may also work in other layered materials for high-performance sodium-ion storage. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Chao, Dongliang Zhu, Changrong Yang, Peihua Xia, Xinhui Liu, Jilei Wang, Jin Fan, Xiaofeng Savilov, Serguei V. Lin, Jianyi Fan, Hong Jin Shen, Ze Xiang |
| format |
Article |
| author |
Chao, Dongliang Zhu, Changrong Yang, Peihua Xia, Xinhui Liu, Jilei Wang, Jin Fan, Xiaofeng Savilov, Serguei V. Lin, Jianyi Fan, Hong Jin Shen, Ze Xiang |
| author_sort |
Chao, Dongliang |
| title |
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| title_short |
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| title_full |
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| title_fullStr |
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| title_full_unstemmed |
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance |
| title_sort |
array of nanosheets render ultrafast and high-capacity na-ion storage by tunable pseudocapacitance |
| publishDate |
2017 |
| url |
https://hdl.handle.net/10356/83885 http://hdl.handle.net/10220/42866 |
| _version_ |
1725985630598463488 |