In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives

In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives

A combined Lewis acid system comprising of two or more Lewis acids occasionally exhibits augmented catalytic activity in organic transformations which are otherwise unrealizable by either of the components exclusively. On the other hand, the efficient construction of multiple new C-C bonds and polyc...

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Main Authors: Zhang, Qiu-Chi, Zhang, Wen-Wei, Shen, Liang, Shen, Zhi-Liang, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2018
Subjects:
Combined Lewis acid
Indium
Online Access:https://hdl.handle.net/10356/84294
http://hdl.handle.net/10220/45108
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-842942023-02-28T19:31:18Z In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives Zhang, Qiu-Chi Zhang, Wen-Wei Shen, Liang Shen, Zhi-Liang Loh, Teck-Peng School of Physical and Mathematical Sciences Combined Lewis acid Indium A combined Lewis acid system comprising of two or more Lewis acids occasionally exhibits augmented catalytic activity in organic transformations which are otherwise unrealizable by either of the components exclusively. On the other hand, the efficient construction of multiple new C-C bonds and polycyclic structures in minimal steps remains a subject of great interest in both academia and industry. Herein we report an efficient method to assemble aryldihydronaphthalene derivatives via a cascade reaction of diarylalkynes with acrylates under the catalysis of a combined Lewis acid derived from In(III) salt and TMSBr. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Published version 2018-07-18T08:20:39Z 2019-12-06T15:42:16Z 2018-07-18T08:20:39Z 2019-12-06T15:42:16Z 2018 Journal Article Zhang, Q.-C., Zhang, W.-W., Shen, L., Shen, Z.-L., & Loh, T.-P. (2018). In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives. Molecules, 23(4), 979-. 1420-3049 https://hdl.handle.net/10356/84294 http://hdl.handle.net/10220/45108 10.3390/molecules23040979 en Molecules © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). 11 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Combined Lewis acid
Indium
spellingShingle Combined Lewis acid
Indium
Zhang, Qiu-Chi
Zhang, Wen-Wei
Shen, Liang
Shen, Zhi-Liang
Loh, Teck-Peng
In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
description A combined Lewis acid system comprising of two or more Lewis acids occasionally exhibits augmented catalytic activity in organic transformations which are otherwise unrealizable by either of the components exclusively. On the other hand, the efficient construction of multiple new C-C bonds and polycyclic structures in minimal steps remains a subject of great interest in both academia and industry. Herein we report an efficient method to assemble aryldihydronaphthalene derivatives via a cascade reaction of diarylalkynes with acrylates under the catalysis of a combined Lewis acid derived from In(III) salt and TMSBr.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Zhang, Qiu-Chi
Zhang, Wen-Wei
Shen, Liang
Shen, Zhi-Liang
Loh, Teck-Peng
format Article
author Zhang, Qiu-Chi
Zhang, Wen-Wei
Shen, Liang
Shen, Zhi-Liang
Loh, Teck-Peng
author_sort Zhang, Qiu-Chi
title In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
title_short In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
title_full In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
title_fullStr In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
title_full_unstemmed In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives
title_sort in(iii)-tmsbr-catalyzed cascade reaction of diarylalkynes with acrylates for the synthesis of aryldihydronaphthalene derivatives
publishDate 2018
url https://hdl.handle.net/10356/84294
http://hdl.handle.net/10220/45108
_version_ 1759856503608573952

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