Synthesis of block copolymers of varying architecture through suppression of transesterification during coordinated anionic ring opening polymerization
Well-defined di- and triblock copolymers consisting of ε-caprolactone (CL), L-lactide (LA), and trimethylene carbonate (TMC) were synthesized via “PLA first route” in coordinated anionic ring opening polymerization/copolymerization (CAROP) with tin (II) octoate as catalyst. The desired block structu...
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Main Authors: | , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/85276 http://hdl.handle.net/10220/16939 |
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Institution: | Nanyang Technological University |
Language: | English |