Incorporation of conductive internal additives within electrocuring adhesives

Incorporation of conductive internal additives within electrocuring adhesives

Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into...

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Bibliographic Details
Main Authors: Gan, Lu, Tan, Nigel Chew Shun, Steele, Terry W. J.
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2019
Subjects:
DRNTU::Engineering::Materials
Internal
Adhesives
Online Access:https://hdl.handle.net/10356/85346
http://hdl.handle.net/10220/48194
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Institution: Nanyang Technological University
Language: English
Description
Summary:Aryl diazirine-grafted polyamidoamine (Dz-g-PAMAM) was recently investigated as an adhesive cured with low voltage potentials, leading to a concept of electrocuring adhesive. Ferrocene is a well-known redox active compound with a high degree of electron reversibility. Ferrocene is incorporated into the electrocuring adhesive as a conductive internal additive, attempting to improve the electron transfer efficiency. In this work, the synthesis of co-grafted Dz-g-Fc-g-PAMAM is confirmed by NMR and UV/Visible absorbance compares the optical properties with and without the ferrocene internal additive.

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