Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications

Colloidal nanoparticles (NPs) containing near-infrared-fluorescent J-aggregates (JAGGs) of pyrrolopyrrole cyanines (PPcys) stabilized by amphiphilic block co-polymers were prepared in aqueous medium. JAGG formation can be tuned by means of the chemical structure of PPcys, the concentration of chromo...

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Main Authors: Yang, Cangjie, Wang, Xiaochen, Wang, Mingfeng, Xu, Keming, Xu, Chenjie
其他作者: School of Chemical and Biomedical Engineering
格式: Article
語言:English
出版: 2017
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在線閱讀:https://hdl.handle.net/10356/85470
http://hdl.handle.net/10220/43723
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機構: Nanyang Technological University
語言: English
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spelling sg-ntu-dr.10356-854702023-12-29T06:46:29Z Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications Yang, Cangjie Wang, Xiaochen Wang, Mingfeng Xu, Keming Xu, Chenjie School of Chemical and Biomedical Engineering Aggregation Colloids Colloidal nanoparticles (NPs) containing near-infrared-fluorescent J-aggregates (JAGGs) of pyrrolopyrrole cyanines (PPcys) stabilized by amphiphilic block co-polymers were prepared in aqueous medium. JAGG formation can be tuned by means of the chemical structure of PPcys, the concentration of chromophores inside the polymeric NPs, and ultrasonication. The JAGG NPs exhibit a narrow emission band at 773 nm, a fluorescence quantum yield comparable to that of indocyanine green, and significantly enhanced photostability, which is ideal for long-term bioimaging. MOE (Min. of Education, S’pore) Accepted version 2017-09-12T04:02:56Z 2019-12-06T16:04:18Z 2017-09-12T04:02:56Z 2019-12-06T16:04:18Z 2017 Journal Article Yang, C., Wang, X., Wang, M., Xu, K., & Xu, C. (2017). Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications. Chemistry - A European Journal, 23(18), 4310-4319. 0947-6539 https://hdl.handle.net/10356/85470 http://hdl.handle.net/10220/43723 10.1002/chem.201604741 en Chemistry - A European Journal © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemistry - A European Journal, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1002/chem.201604741]. 10 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Aggregation
Colloids
spellingShingle Aggregation
Colloids
Yang, Cangjie
Wang, Xiaochen
Wang, Mingfeng
Xu, Keming
Xu, Chenjie
Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
description Colloidal nanoparticles (NPs) containing near-infrared-fluorescent J-aggregates (JAGGs) of pyrrolopyrrole cyanines (PPcys) stabilized by amphiphilic block co-polymers were prepared in aqueous medium. JAGG formation can be tuned by means of the chemical structure of PPcys, the concentration of chromophores inside the polymeric NPs, and ultrasonication. The JAGG NPs exhibit a narrow emission band at 773 nm, a fluorescence quantum yield comparable to that of indocyanine green, and significantly enhanced photostability, which is ideal for long-term bioimaging.
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Yang, Cangjie
Wang, Xiaochen
Wang, Mingfeng
Xu, Keming
Xu, Chenjie
format Article
author Yang, Cangjie
Wang, Xiaochen
Wang, Mingfeng
Xu, Keming
Xu, Chenjie
author_sort Yang, Cangjie
title Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
title_short Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
title_full Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
title_fullStr Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
title_full_unstemmed Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications
title_sort robust colloidal nanoparticles of pyrrolopyrrole cyanine j-aggregates with bright near-infrared fluorescence in aqueous media: from spectral tailoring to bioimaging applications
publishDate 2017
url https://hdl.handle.net/10356/85470
http://hdl.handle.net/10220/43723
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